Platinum and platinum based nanoalloys synthesized by wet chemistry
Author:
Affiliation:
1. Sorbonne Universités
2. UPMC Univ Paris 06
3. UMR 8233
4. MONARIS
5. Paris
6. Centre de Recherche sur la Matière Divisée
7. CRMD
8. Université d'Orléans
9. CNRS
10. Orléans Cedex 2
11. UMR 7616
12. Laboratoire de Chimie Théorique
Abstract
Platinum nanocrystals and their derivatives with palladium and cobalt are of fundamental interest due to their wide field of application in chemistry and physics. Their properties are strongly dependent on their shape and composition. However the chemical route is far from allowing control of both shape and composition. In this paper, we show both experimentally and theoretically the important role of the interaction of small adsorbed molecules on the shape but also on the composition. This has been studied by comparing the case of pure palladium and platinum nanocrystals and the case of PtPd and PtCo nanoalloys synthesized by the liquid–liquid phase transfer method.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/FD/C5FD00002E
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