High-pressure synthesis, spin-glass behaviour, and magnetocaloric effects in FexTi2S4 heideite sulphides-Reference-Cited by-同舟云学术

High-pressure synthesis, spin-glass behaviour, and magnetocaloric effects in Fe_xTi₂S₄ heideite sulphides

Published:2022 Issue:42 Volume:10 Page:15929-15940
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Silva Jr R. S.¹²^ORCID,Gainza J.¹^ORCID,Rodrigues J. E.¹³^ORCID,Martínez L.¹^ORCID,Céspedes E.¹^ORCID,Nemes N. M.¹⁴^ORCID,Martínez J. L.¹^ORCID,Alonso J. A.¹^ORCID

Affiliation:

1. Instituto de Ciencia de Materiales de Madrid (ICMM), CSIC, E-28049 Madrid, Spain

2. Department of Physics, Federal University of Sergipe, 49100-000, São Cristóvão, SE, Brazil

3. European Synchrotron Radiation Facility (ESRF), 71 Avenue des Martyrs, 38000 Grenoble, France

4. Departamento de Física de Materiales, Universidad Complutense de Madrid, E-28040 Madrid, Spain

Abstract

A rapid high-pressure preparation method (3.5 GPa) yields FexTi2S4 Heideite-type phase. Magnetism offers a complex scenario with AFM to FM-like interactions. The magnetocaloric effect yields significant entropy and relative cooling power.

Funder

Ministerio de Ciencia e Innovación

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TC/D2TC02160A

Reference59 articles.

1. Electrochemical Properties and Reaction Mechanism of NiTi2S4 Ternary Metal Sulfide as an Anode for Lithium Ion Battery

2. Large magnetocaloric effect in spinel CdCr2S4