Constructing a square-like copper cluster to boost C–C coupling for CO<sub>2</sub> electroreduction to ethylene-Reference-Cited by-同舟云学术

Constructing a square-like copper cluster to boost C–C coupling for CO₂ electroreduction to ethylene

Published:2023 Issue:36 Volume:11 Page:19444-19454
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Zhao Tiantian¹,Yan Tingyu¹,Sun Yuting¹,Wang Zhongxu¹,Cai Qinghai¹^ORCID,Zhao Jingxiang¹^ORCID,Chen Zhongfang²^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Key Laboratory of Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin 150025, China

2. Department of Chemistry, University of Puerto Rico, Rio Piedras Campus, San Juan, Puerto Rico 00931, USA

Abstract

By DFT computations, we proposed Cu5@MoS2—an anchored Cu5 cluster on defective MoS2—as a promising catalyst for CO2-to-ethylene conversion. With distinctive square-like sites, Cu5@MoS2 demonstrates remarkable activity and selectivity, particularly in alkaline conditions.

Funder

Oklahoma Humanities Council

Natural Science Foundation of Heilongjiang Province

U.S. Department of Energy

Harbin Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D3TA03630H

Reference93 articles.