Transformation of 5-acylated <i>N</i>-fluoroalkyl-1,2,3-triazoles to trifluoromethylated ring-fused isoquinolines, 1,3-oxazines, and 1,3-oxazin-6-ones <i>via</i> ketenimines-Reference-Cited by-同舟云学术

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Transformation of 5-acylated N-fluoroalkyl-1,2,3-triazoles to trifluoromethylated ring-fused isoquinolines, 1,3-oxazines, and 1,3-oxazin-6-ones via ketenimines

Published:2024 Issue:37 Volume:14 Page:26938-26942
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Janecký Lukáš¹²^ORCID,Klepetářová Blanka¹,Beier Petr¹^ORCID

Affiliation:

1. The Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nam. 2, 16610 Prague 6, Czech Republic

2. Department of Organic Chemistry, Faculty of Science, Charles University, Hlavova 2030/8, 128 43 Prague 2, Czech Republic

Abstract

A new synthetic approach towards trifluoromethylated heterocycles, based on the reaction of 5-acylated N-fluoroalkyl substituted 1,2,3-triazoles under microwave heating, proceeding via ketenimines is presented.

Funder

Akademie Věd České Republiky

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA04794J

Reference35 articles.

1. Transition-Metal-Free β-C–H Bond Carbonylation of Enamides or Amides with a Trifluoromethyl Group as CO Surrogate for the Synthesis of 1,3-Oxazin-6-ones

2. Potentiometric study on acid properties of some 4-hydroxy-6H-1,3-oxazin-6-ones. Structure-biological activity relationship

3. Copper Catalyzed Inverse Electron Demand [4+2] Cycloaddition for the Synthesis of Oxazines

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