Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones-Reference-Cited by-同舟云学术

Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones

Published:2022 Issue:36 Volume:13 Page:10743-10751
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kurosawa Miki B.¹,Kato Kenta¹,Muto Kei²^ORCID,Yamaguchi Junichiro¹^ORCID

Affiliation:

1. Department of Applied Chemistry, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo 162-0041, Japan

2. Waseda Institute for Advanced Study, Waseda University, 513 Wasedatsurumakicho, Shinjuku, Tokyo 162-0041, Japan

Abstract

We succeeded in synthesizing five different types of multiply arylated alkanes from diarylketones in a single step. The key for this method is the generation of diarylphosphinates via a phospha-Brook rearrangement of ketones with phosphine oxide.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Corporation

Waseda University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03720C

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