Reversible trans ⇌ cis photoisomerizations of [Re(CO)3(ph2phen)(stpyCN)]+ towards molecular machines-Reference-Cited by-同舟云学术

Reversible trans ⇌ cis photoisomerizations of [Re(CO)3(ph2phen)(stpyCN)]+ towards molecular machines

Published:2017 Issue:30 Volume:46 Page:9951-9958
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zanoni Kassio P. S.¹²³⁴⁵^ORCID,Murakami Iha Neyde Y.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Photochemistry and Energy Conversion

2. Departamento de Química Fundamental

3. Instituto de Química

4. Universidade de São Paulo – USP

5. São Paulo

Abstract

The fac-[Re(CO)₃(ph₂phen)(stpyCN)]⁺ complex is capable of switching through extended trans- and contracted cis-configurations upon irradiation under proper energies.

Funder

São Paulo Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01648D

Reference30 articles.

1. Mechanism of visible-light photoisomerization of a rhenium(i) carbonyl–diimine complex

2. Spectroscopic trends in a series of Re(I) α-diimine complexes as a function of the antenna/photoisomerizable ligands: a TD-DFT and MS-CASPT2 study

3. Highlights of metal ion-based photochemical switches

4. Optomechanical trans-to-cis and cis-to-trans isomerization and unusual photophysical behavior of fac-[Re(CO)3(phen)(CNstpy)]+

5. Photoswitching tetranuclear rhenium(i) tricarbonyl diimine complexes with a stilbene-like bridging ligand

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