A giant hybrid organic–inorganic octahedron from a narrow rim carboxylate calixarene

Author:

Machado dos Santos Fernando1234,Edivirges Alvarenga Meiry1234,Valdo Ana Karoline Silva Mendanha1234,Rabelo Renato5678,Cangussu de Castro Gomes Danielle1234ORCID,de Fátima Ângelo910114,Vinicius Costa Lara Thiago910114,da Silva Cleiton Moreira910114,Tasso Thiago Teixeira910114,Neto João Honorato Araujo912134ORCID,Batista Alzir Azevedo912134ORCID,Ayala Alejandro Pedro141516174ORCID,Ellena Javier Alcides1819134ORCID,Ferraz Guimarães Vinicius1234,Maria Alves Oliveira Cecília1234,da Silva Lidya Cardozo1234,Gontijo Vaz Boniek1234ORCID,Terra Martins Felipe1234ORCID

Affiliation:

1. Institute of Chemistry

2. Federal University of Goias

3. Goiania

4. Brazil

5. Institute of Molecular Science (ICMol)

6. University of Valencia

7. Paterna 46980

8. Spain

9. Department of Chemistry

10. Federal University of Minas Gerais

11. Belo Horizonte

12. Federal University of Sao Carlos

13. Sao Carlos

14. Department of Physics

15. Federal University of Ceara

16. CP 6030

17. Fortaleza

18. São Carlos Institute of Physics

19. University of São Paulo

Abstract

Here we discovered an unprecedented giant octahedral coordination compound bearing 16 Zn2+, 12 Na+, 8 O2−, 4 OH, 13 H2O and 6 L4− ligands [L4− = fully deprotonated tetra(carboxymethoxy)calix[4]arene].

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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