Polarization-induced charge separation in conjugated microporous polymers for efficient visible light-driven C-3 selenocyanation of indoles-Reference-Cited by-同舟云学术

Polarization-induced charge separation in conjugated microporous polymers for efficient visible light-driven C-3 selenocyanation of indoles

Published:2021 Issue:15 Volume:12 Page:5631-5637
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xie Qiujian¹²³⁴⁵,Yang Yumin⁶⁷⁸⁵,Zhang Weijie¹²³⁴⁵,Gao Zhu¹²³⁴⁵,Li Xiaofeng¹²³⁴⁵,Tang Juntao¹²³⁴⁵,Pan Chunyue¹²³⁴⁵,Yu Guipeng¹²³⁴⁵^ORCID

Affiliation:

1. Hunan Key Laboratory of Micro & Nano Materials Interface Science

2. College of Chemistry and Chemical Engineering

3. Central South University

4. Changsha 410083

5. P. R. China

6. Queen Mary University of London Engineering School

7. Northwestern Polytechnical University

8. Xian 710072

Abstract

An internal electric field was used to promote the charge separation of conjugated microporous polymers (CMPs). Those with the largest dipole moment exhibited high efficiency in C-3 selenocyanation of indoles under visible-light and room temperature.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06951E

Reference53 articles.

1. Organoselenium Chemistry: Role of Intramolecular Interactions

2. Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

3. Palladium-Catalyzed Aryl Amination–Heck Cyclization Cascade: A One-Flask Approach to 3-Substituted Indoles