Self-assembly of long-chain quaternary ammonium cations in a hybrid inorganic–organic material with one-dimensional polymeric tribromidoplumbate(II)
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Published:2012-06-13
Issue:7
Volume:68
Page:m173-m176
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ISSN:0108-2701
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Container-title:Acta Crystallographica Section C Crystal Structure Communications
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language:
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Short-container-title:Acta Crystallogr C
Author:
Hodorowicz Maciej A.,Piaskowska Agata,Stadnicka Katarzyna M.
Abstract
catena-Poly[benzyldecyldimethylammonium [plumbate(II)-tri-μ-bromido]], {(C19H34N)[PbBr3]}n, crystallizes as an inorganic–organic hybrid following monoclinic space-group symmetryP21/c. The structure consists of extended chains running along the [001] direction and built of [PbBr3]−units. These inorganic chains are separated by interdigitated ammonium cations which form hydrophilic layers through weak C—H...Br interactions. The architecture is essentialy the same as found forn-alkylbenzyldimethylammonium bromides.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Cited by
1 articles.
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