Self-assembly of long-chain quaternary ammonium cations in a hybrid inorganic–organic material with one-dimensional polymeric tribromidoplumbate(II)

Author:

Hodorowicz Maciej A.,Piaskowska Agata,Stadnicka Katarzyna M.

Abstract

catena-Poly[benzyldecyldimethylammonium [plumbate(II)-tri-μ-bromido]], {(C19H34N)[PbBr3]}n, crystallizes as an inorganic–organic hybrid following monoclinic space-group symmetryP21/c. The structure consists of extended chains running along the [001] direction and built of [PbBr3]units. These inorganic chains are separated by interdigitated ammonium cations which form hydrophilic layers through weak C—H...Br interactions. The architecture is essentialy the same as found forn-alkylbenzyldimethylammonium bromides.

Publisher

International Union of Crystallography (IUCr)

Subject

General Biochemistry, Genetics and Molecular Biology,General Medicine

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites;Journal of the American Chemical Society;2018-09-13

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