Electron diffraction characterization of a new metastable Al2Cu phase in an Al–Cu friction stir weld

Abstract

The space group of a new metastable orthorhombic Al2Cu phase, located in the Al-rich interfacial region of an Al–Cu friction stir weld, was unambiguously identified asIc2mby a recently developed systematic method combining precession electron diffraction and convergent-beam electron diffraction. This metastable phase has the same tetragonal lattice as its stable θ-Al2Cu counterpart (tetragonal,I4/mcm, No. 140). The tetragonal-to-orthorhombic symmetry lowering is due to slight modifications of the atomic positions in the unit cell. This metastable phase can be transformed into the stable θ-Al2Cu phase byin situirradiation within the transmission electron microscope.