Abstract
In the title compound, C19H27F3N2OS2, the dihedral angle between the benzene ring and dithiocarbamate group is 67.00 (9)° and a weak intramolecular N—H...S interaction generates anS(7) ring. Thetert-butyl group is disordered over two orientations in a 0.628 (14):0.372 (14) ratio. In the crystal, inversion dimers linked by pairs of weak C—H...O interactions generateR22(20) loops and the aromatic rings of neighbouring pairs of molecules are involved in very weak π–π stacking interactions [centroid–centroid separation = 4.0042 (13) Å].
Funder
King Saud University, Deanship of Scientific Research, Research Chairs
Engineering and Physical Sciences Research Council
Publisher
International Union of Crystallography (IUCr)
Subject
Rehabilitation,Physical Therapy, Sports Therapy and Rehabilitation,General Medicine
Reference9 articles.
1. Agilent (2014). CrysAlis PRO. Agilent Technologies, Yarnton, England.
2. Cambridge Soft (2001). CHEMDRAW Ultra. Cambridge Soft Corporation, Cambridge, Massachusetts, USA.
3. Chatgilialoglu, C. & Asmus, K.-D. (1990). Sulfur-Centered Reactive Intermediates in Chemistry and Biology. Vol. 179, NATO-ASI Series. New York and London: Plenum.
4. Crystal structure of 4-(2,2-dimethylpropanamido)pyridin-3-ylN,N-diisopropyldithiocarbamate
5. WinGXandORTEP for Windows: an update