Hexabromo- and hexaiododisilane: small and simple molecules showing completely different crystal structures

Abstract

The title compounds were prepared through dephenylation of hexaphenyldisilane with acetyl bromide or acetyl iodide in the presence of the corresponding aluminium halide. Both substances were purifiedviasublimation and, for the first time, single crystals of hexabromodisilane, Si2Br6, and a new polymorph of hexaiododisilane, Si2I6, could be isolated. Molecules of Si2Br6are located on a special position of site symmetry 2/mwith a quarter of a molecule in the asymmetric unit. Molecules of Si2I6are located on a special position of site symmetry \overline{3} with a sixth of a molecule in the asymmetric unit. The bond lengths of Si2Br6and Si2I6are in the usual ranges and both molecules adopt a staggered conformation. It is interesting to note that Si2Br6and Si2I6do not form isomorphous structures. Moreover, an orthorhombic polymorph of the present structure of Si2I6is already known [Jansen & Friede (1996).Acta Cryst.C52, 1333–1334]. Although the title compounds feature such small and simple molecules they show completely different crystal structures.