Author:
Richers Casseday P.,Bertke Jeffery A.,Gray Danielle L.,Rauchfuss Thomas B.
Abstract
The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetylacetonate), crystallizes in the orthorhombicPbcaspace group with one half of the molecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C—H...Cl intermolecular interactions result in a two-dimensional layered structure parallel to theacplane.
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Reference23 articles.
1. Synthesis and characterisation of new iron(III) compounds containing the first examples of pendant-armed alcohols of cyclen
2. Bruker (2012). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
3. Bruker (2013). APEX2, SAINT, SHELXTL, XCIF, and XPREP. Bruker AXS Inc., Madison, Wisconsin, USA.
4. Organotin catalysts in organosilicon chemistry
5. CrystalMaker (2014). CrystalMaker. CrystalMaker Software Ltd, Bicester, Oxfordshire, England. http://www.crystalmaker.com.
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献