Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro[(4-ferrocenylphenyl)imino]methyl}-4-ferrocenylaniline N,N-dimethylformamide monosolvate-Reference-Cited by-同舟云学术

Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro[(4-ferrocenylphenyl)imino]methyl}-4-ferrocenylaniline N,N-dimethylformamide monosolvate

Published:2024-02-02 Issue:3 Volume:80 Page:262-266
ISSN:2056-9890
Container-title:Acta Crystallographica Section E Crystallographic Communications
language:
Short-container-title:Acta Crystallogr E Cryst Commun

Author:

Sghyar Riham,Bentama Abdeslem,Haoudi Amal,Mazzah Ahmed^ORCID,Mague Joel T.^ORCID,Hökelek Tuncer^ORCID,EL Hadrami El Mestafa^ORCID,Sebbar Nada Kheira

Abstract

The title molecule, [Fe2(C5H5)2(C23H17ClN2)]·C3H7NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C—H...π(ring) interactions lead to the formation of layers, which are connected by further C—H...π(ring) interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H...H (60.2%) and H...C/C...H (27.0%) interactions. Hydrogen bonding, C—H...π(ring) interactions and van der Waals interactions dominate the crystal packing.

Funder

Tulane University

Hacettepe University Scientific Research Project Unit

Publisher

International Union of Crystallography (IUCr)

Link

https://journals.iucr.org/e/issues/2024/03/00/ox2002/ox2002.pdf

Reference34 articles.

1. In silico and in vivo investigation of ferrocene-incorporated acyl ureas and homoleptic cadmium carboxylate derivatives for anticonvulsant, anxiolytic, and sedative potential

2. Organometallic compounds in oncology: implications of novel organotins as antitumor agents

3. Brandenburg, K. & Putz, H. (2012). DIAMOND, Crystal Impact GbR, Bonn, Germany.

4. Bruker (2021). APEX4 and SAINT. Bruker AXS LLC, Madison, Wisconsin, USA.

5. Direct electrochemistry of glucose oxidase immobilized on a hexagonal mesoporous silica-MCM-41 matrix