Abstract
The molecular bis-chelate complex (2-{[(2-hydroxyethyl-κO)amino-κN]methyl}-6-methoxyphenolato-κO)(2-{[(2-hydroxyethyl)imino-κN]methyl}-6-methoxyphenolato-κO)copper(II), [Cu(C10H14NO3)(C10H12NO3)] or [Cu(HL
im)(HL
am); HL
im = C10H14NO3; HL
am = C10H12NO3, represents the first compound containing a salicylidene-2-ethanolamine type ligand in both imino HL
im (Schiff base) and amino HL
am (reduced Schiff base) forms that has been structurally characterized on the basis of X-ray data. Two molecules of the monodeprotonated ligands coordinate the CuII ion in an (N,O
phen)-bidentate and an (N,O
phen,O
alc)-tridentate fashion in the case of the imino and amino forms, respectively. The shape of the CuN2O3 coordination polyhedron is a distorted square-pyramid (geometry index τ5 = 0.26). Intermolecular N—H...O and O—H...O hydrogen bonds, involving H atoms of the amino and hydroxyethyl groups, create a two-dimensional supramolecular array extending parallel to (010).
Funder
Ministry of Education and Science of Ukraine
Slovenian Research Agency
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
1 articles.
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