Abstract
In the title compound, C14H8Br2FN3O2, the nitro-substituted benzene ring and the 4-fluorophenyl ring form a dihedral angle of 65.73 (7)°. In the crystal, molecules are linked into chains by C—H...O hydrogen bonds running parallel to the c-axis direction. The crystal packing is consolidated by C—F...π interactions and π–π stacking interactions, and short Br...O [2.9828 (13) Å] contacts are observed. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H...H (17.4%), O...H/H...O (16.3%), Br...H/H...Br (15.5%), Br...C/C...Br (10.1%) and F...H/H...F (8.1%) contacts.
Funder
Science Development Foundation of the President of Azerbaijan
Publisher
International Union of Crystallography (IUCr)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Cited by
6 articles.
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3. Structural Organization of Dibromodiazadienes in the Crystal and Identification of Br···O Halogen Bonding Involving the Nitro Group;Molecules;2022-08-11
4. Crystal structure and Hirshfeld surface analysis of a new polymorph of (E)-2-(4-bromophenyl)-1-[2,2-dibromo-1-(3-nitrophenyl)ethenyl]diazene;Acta Crystallographica Section E Crystallographic Communications;2022-07-14
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