Author:
Ehrenberg H.,Hartmann T.,Wltschek G.,Fuess H.,Morgenroth W.,Krane H.-G.
Abstract
The crystal structure of Tm5Re2O12, pentathulium dirhenium dodecaoxide, was determined by synchrotron diffraction on a reticular merohedral twin, revealing space group C2/m with a = 12.3717 (7), b = 5.6744 (3), c = 7.4805 (4) Å, β = 107.816 (2)° and Z = 2. Distorted ReO6 octahedra form chains with alternating rhenium–rhenium distances of 2.455 (1) and 3.219 (1) Å. Early reports on Ln2ReO5 compounds are critically reviewed in the light of our results for Tm5Re2O12.
Publisher
International Union of Crystallography (IUCr)
Subject
General Biochemistry, Genetics and Molecular Biology,General Medicine
Cited by
50 articles.
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