Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Link
http://www.nature.com/articles/s41467-018-08253-z.pdf
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3. Morandi, B. & Carreira, E. M. Rhodium-catalyzed cyclopropenation of alkynes: synthesis of trifluoromethyl-substituted cyclopropenes. Angew. Chem. Int. Ed. 49, 4294–4296 (2010).
4. Künzi, S. A., Morandi, B. & Carreira, E. M. Preparation of trifluoromethyl-substituted aziridines with in situ generated CF3CHN2. Org. Lett. 14, 1900–1901 (2012).
5. Li, F., Nie, J., Sun, L., Zheng, Y. & Ma, J. A. Silver-mediated cycloaddition of alkynes with CF3CHN2: highly regioselective synthesis of 3-trifluoromethylpyrazoles. Angew. Chem. Int. Ed. 52, 6255–6258 (2013).
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