Author:
Carlomagno I.,Zeller P.,Amati M.,Aquilanti G.,Prenesti E.,Marussi G.,Crosera M.,Adami G.
Abstract
AbstractFour gold coins minted in the V century have been studied with non-destructive synchrotron radiation techniques, namely X-Ray Fluorescence (XRF) and X-ray Absorption Near Edge Spectroscopy (XANES). XRF data analyzed coupling standard and statistical methods were used to distinguish the composition of the alloy constituting the coins from that of successive deposits processes. Our analysis presents a quantification of the trace elements present in the metallic alloy providing interesting details for historical insight. Furthermore, on the basis of the XRF maps, some regions of interest were selected for XANES at the K-edge of Fe. Our analysis of the Fe spectra points out two main phases which can be related to Fe oxides naturally present in soil. From the relative abundance of these oxides, information on the site where the coins were found can be obtained, providing additional information on their fate across the centuries.
Publisher
Springer Science and Business Media LLC
Reference30 articles.
1. Janssens, K. et al. Use of microscopic xrf for non-destructive analysis in art and archaeometry. X-Ray Spectrom. Int. J. 29, 73–91 (2000).
2. Adams, F., Janssens, K. & Snigirev, A. Microscopic x-ray fluorescence analysis and related methods with laboratory and synchrotron radiation sources. J. Anal. At. Spectrom. 13, 319–331 (1998).
3. Jark, W., Eichert, D., Luehl, L. & Gambitta, A. Optimisation of a compact optical system for the beamtransport at the x-ray fluorescence beamline at elettra for experiments with small spots. In Advances in X-Ray/EUV optics and components IX, vol. 9207, 92070G (International Society for Optics and Photonics, 2014).
4. Farges, F. & Cotte, M. X-ray absorption spectroscopy and cultural heritage: highlights and perspectives. In X-Ray Absorption and X-Ray Emission Spectroscopy: Theory and Applications, 609–636 (2016).
5. Bigham, J., Fitzpatrick, R. W. & Schulze, D. Iron oxides. Soil Mineral. Environ. Appl. 7, 323–366 (2002).
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献