Asymmetric allylic C(sp3)–C(sp3) bond functionalization
Author:
Funder
Science and Technology Commission of Shanghai Municipality
National Natural Science Foundation of China
Natural Science Foundation of Ningbo
Publisher
Springer Science and Business Media LLC
Link
https://www.nature.com/articles/s44160-024-00556-y.pdf
Reference5 articles.
1. Bi, X., Zhang, Q. & Gu, Z. Transition-metal-catalyzed carbon-carbon bond activation in asymmetric synthesis. Chin. J. Chem. 39, 1397–1412 (2021). A review article that summarizes advances in asymmetric C–C bond activation.
2. Wen, L. et al. Multiplicative enhancement of stereoenrichment by a single catalyst for deracemization of alcohols. Science 382, 458–464 (2023). This paper reports a radical route to realize the activation of unstrained asymmetric C(sp3)–C(sp3) bonds.
3. Nogi, K. & Yorimitsu, H. Carbon−carbon bond cleavage at allylic positions: retro-allylation and deallylation. Chem. Rev. 121, 345–364 (2021). A review article that presents advances in allylic C–C bond cleavage.
4. Higashida, K., Smail, V., Nagae, H., Carpentier, J.-F. & Mashima, K. Nickel-catalyzed asymmetric allylic alkylation of β‑dicarbonyl compounds via C−C bond activation of 2‑allylated cyclic 1,3-diketones. ACS Catal. 13, 2156–2161 (2023). This paper reports the formation of a stereogenic centre at a position besides the cleaved allylic C(sp3)–C(sp3) bond.
5. Granberg, K. L. & Bäckvall, J.-E. Isomerization of (π-allyl)palladium complexes via nucleophilic displacement by palladium(0). A common mechanism in palladium(0)-catalyzed allylic substitution. J. Am. Chem. Soc. 114, 6858–6863 (1992). This paper reports the general mechanism for enantioconvergence in Pd-catalysed allylic substitutions with racemic electrophiles.
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