Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(v)–dinitrogen complex
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Chemical Engineering,General Chemistry
Link
http://www.nature.com/articles/s41557-019-0306-x.pdf
Reference48 articles.
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3. Andrews, L., Wang, X., Gong, Y., Vlaisavljevich, B. & Gagliardi, L. Infrared spectra and electronic structure calculations for the NUN(NN)1–5 and NU(NN)1–6 complexes in solid argon. Inorg. Chem. 52, 9989–9993 (2013).
4. Burford, R. J. & Fryzuk, M. D. Examining the relationship between coordination mode and reactivity of dinitrogen. Nat. Rev. Chem. 1, 0026 (2017).
5. Dell’Amico, D. B., Calderazzo, F., Marchetti, F. & Merlino, S. Synthesis and molecular structure of [Au4Cl8], and the isolation of [Pt(CO)Cl5]– in thionyl chloride. J. Chem. Soc. Dalton Trans. 1982, 2257–2260 (1982).
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