Ni-catalysed assembly of axially chiral alkenes from alkynyl tetracoordinate borons via 1,3-metallate shift
Author:
Funder
National Natural Science Foundation of China
Natural Science Foundation of Fujian Province
Publisher
Springer Science and Business Media LLC
Link
https://www.nature.com/articles/s41557-023-01396-7.pdf
Reference71 articles.
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2. Ishikura, M. & Terashima, M. A new pathway into [b]-annelated indole derivatives through trialkyl(1-methyl-2-indolyl) borates. J. Chem. Soc. J. Chem. Soc. 1991, 1219–1221 (1991).
3. Kischkewitz, M., Okamoto, K., Mück-Lichtenfeld, C. & Studer, A. Radical-polar crossover reactions of vinylboron ate complexes. Science 355, 936–938 (2017).
4. Silvi, M., Sandford, C. & Aggarwal, V. K. Merging photoredox with 1,2-metallate rearrangements: the photochemical alkylation of vinyl boronate complexes. J. Am. Chem. Soc. 139, 5736–5739 (2017).
5. Yang, K. & Song, Q. Tetracoordinate boron intermediates enable unconventional transformations. Acc. Chem. Res. 54, 2298–2312 (2021).
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