Novel Rectangular [Fe4(μ4-OHO)(μ-OH)2]7+ versus “Butterfly” [Fe4(μ3-O)2]8+ Core Topology in the FeIII/RCO2-/phen Reaction Systems (R = Me, Ph; phen = 1,10-Phenanthroline): Preparation and Properties of [Fe4(OHO)(OH)2(O2CMe)4(phen)4](ClO4)3, [Fe4O2(O2CPh)7(phen)2](ClO4), and [Fe4O2(O2CPh)8(phen)2]-Reference-Cited by-同舟云学术

Novel Rectangular [Fe4(μ4-OHO)(μ-OH)2]7+ versus “Butterfly” [Fe4(μ3-O)2]8+ Core Topology in the FeIII/RCO2-/phen Reaction Systems (R = Me, Ph; phen = 1,10-Phenanthroline): Preparation and Properties of [Fe4(OHO)(OH)2(O2CMe)4(phen)4](ClO4)3, [Fe4O2(O2CPh)7(phen)2](ClO4), and [Fe4O2(O2CPh)8(phen)2]

Published:2002-11-02 Issue:24 Volume:41 Page:6474-6487
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Boudalis Athanassios K.¹,Lalioti Nikolia¹,Spyroulias Georgios A.¹,Raptopoulou Catherine P.¹,Terzis Aris¹,Bousseksou Azzedine¹,Tangoulis Vassilis¹,Tuchagues Jean-Pierre¹,Perlepes Spyros P.¹

Affiliation:

1. Department of Chemistry, University of Patras, 26504 Patras, Greece, Department of Materials Science, University of Patras, 26504 Patras, Greece, Department of Pharmacy, University of Patras, 26504 Patras, Greece, Institute of Materials Science, NCSR “Demokritos”, 15310 Aghia Paraskevi Attikis, Greece, and Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 205 route de Narbonne, 31077 Toulouse Cedex 04, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic025795k

Reference108 articles.

1. Synthesis, Structures, and Magnetic Properties of Fe2, Fe17, and Fe19 Oxo-Bridged Iron Clusters: The Stabilization of High Ground State Spins by Cluster Aggregates

2. Towards nanostructured arrays of single molecule magnets: new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis †

3. Spin frustration: a hexanuclear ferric complex with a S = 5 ground state

4. Hexanuclear ferric complexes possessing different degrees of spin frustration

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