Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway-Reference-Cited by-同舟云学术

Mechanistic Investigation of Intramolecular Aminoalkene and Aminoalkyne Hydroamination/Cyclization Catalyzed by Highly Electrophilic, Tetravalent Constrained Geometry 4d and 5f Complexes. Evidence for an M−N σ-Bonded Insertive Pathway

Published:2007-04-19 Issue:19 Volume:129 Page:6149-6167
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Stubbert Bryan D.¹,Marks Tobin J.¹

Affiliation:

1. Contribution from the Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0675898

Reference91 articles.

1. Energetics and Mechanism of Organolanthanide-Mediated Aminoalkene Hydroamination/Cyclization. A Density Functional Theory Analysis

2. Organolanthanide constrained geometry complexes modified for catalysis: synthesis, structure, and aminoalkene hydroamination properties of a pyrrolidine-substituted constrained geometry organolutetium complex

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