Kinetic Solvent Effects on Hydrogen-Atom Abstractions:  Reliable, Quantitative Predictions via a Single Empirical Equation1

Author:

Snelgrove Darren W.1,Lusztyk Janusz1,Banks J. T.1,Mulder Peter1,Ingold K. U.1

Affiliation:

1. Contribution from the Steacie Institute for Molecular Sciences, National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario, Canada K1A 0R6, Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario, Canada K1S 5B6, and Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference57 articles.

1. (c) NRCC Research Associate, 1994−1996.

2. See, e.g. Radical Reaction Rates in Solution; Fischer, H., Ed.; Landolt-Börnstein, New Series; Springer-Verlag:  Berlin; 1984; Vol. 13, subvolumes 13a−e (∼2000 pages); 1994; Vol. 18, subvolumes 18a−e2 (∼3000 pages).

3. Experimental evidence for ethylidene-d4

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