How Alkyl Halide Structure Affects E2 and SN2 Reaction Barriers: E2 Reactions Are as Sensitive as SN2 Reactions
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, Swarthmore College, 500 College Avenue, Swarthmore, Pennsylvania 19081, United States
Funder
Camille and Henry Dreyfus Foundation
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo4026644
Reference52 articles.
1. Gas Phase Studies of the Competition between Substitution and Elimination Reactions
2. 44. Mechanism of substitution at a saturated carbon atom. Part XXVI. The rôle of steric hindrance. (Section A) introductory remarks, and a kinetic study of the reactions of methyl, ethyl, n-propyl, isobutyl, and neopentyl bromides with sodium ethoxide in dry ethyl alcohol
3. 50. Mechanism of substitution at a saturated carbon atom. Part XXXII. The rôle of steric hindrance. (Section G) magnitude of steric effects, range of occurrence of steric and polar effects, and place of the wagner rearrangement in nucleophilic substitution and elimination
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