Theoretical Study of Oxidative Addition and Reductive Elimination of 14-Electron d10 ML2 Complexes: A ML2 + CH4 (M = Pd, Pt; L = CO, PH3, L2 = PH‘2CH2CH2PH2) Case Study-Reference-Cited by-同舟云学术

Theoretical Study of Oxidative Addition and Reductive Elimination of 14-Electron d10 ML2 Complexes: A ML2 + CH4 (M = Pd, Pt; L = CO, PH3, L2 = PH‘2CH2CH2PH2) Case Study

Published:1998-06-01 Issue:13 Volume:37 Page:3400-3406
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Su Ming-Der¹,Chu San-Yan¹

Affiliation:

1. Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan, R.O.C.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic970320s

Reference49 articles.

1. Homogeneous catalytic activation of carbon-hydrogen bonds

2. cis-[Bis(dicyclohexylphosphino)ethane]platinum(0) reacts with unactivated carbon-hydrogen bonds

3. [Bis(dicyclohexylphosphino)ethane]platinum(0). Reactions with alkyl, (trimethylsilyl)methyl, aryl, benzyl, and alkynyl carbon-hydrogen bonds

4. Activation of the carbon-hydrogen bonds of benzene by reaction with [bis(dicyclohexylphosphino)ethane]platinum(0), generated by the thermolysis of cis-[bis(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

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