Abiotic Metallofoldamers as Electrochemically Responsive Molecules
Author:
Affiliation:
1. Contribution from the Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja050886c
Reference46 articles.
1. Foldamers: A Manifesto
2. We use Moore's system of nomenclature to distinguish peptidomimetic foldamers from their abiotic analogues. Paraphrasing from pages 3910 and 3944 of ref 2: peptidomimetic foldamer research is defined as a ‘top-down' design approach that involves structural variations of parent chain molecules known to undergo folding reactions. Research on their abiotic analogues employs a ‘bottom-up' design approach, where analogous architectures to biomacromolecules are obtained by backbones that bear little resemblance to natural chains.
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