Highly Enantioselective Catalytic Dynamic Resolution of N-Boc-2-lithiopiperidine: Synthesis of (R)-(+)-N-Boc-Pipecolic Acid, (S)-(−)-Coniine, (S)-(+)-Pelletierine, (+)-β-Conhydrine, and (S)-(−)-Ropivacaine and Formal Synthesis of (−)-Lasubine II and (+)-Cermizine C
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja105772z
Reference15 articles.
1. α-Lithioamine synthetic equivalents from dipole-stabilized carbanions: The t-Boc group as an activator for α′-lithiation of carbamates
2. Asymmetric deprotonations: enantioselective syntheses of 2-substituted tert-(butoxycarbonyl)pyrrolidines
3. An Experimental and Computational Investigation of the Enantioselective Deprotonation of Boc-piperidine
4. Asymmetric Deprotonation of N-Boc Piperidine: React IR Monitoring and Mechanistic Aspects
5. Dynamic resolution of N-Boc-2-lithiopiperidine
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