Synthesis, Structure, and Reactivity of the Sterically Crowded Th3+ Complex (C5Me5)3Th Including Formation of the Thorium Carbonyl, [(C5Me5)3Th(CO)][BPh4]-Reference-Cited by-同舟云学术

Synthesis, Structure, and Reactivity of the Sterically Crowded Th3+ Complex (C5Me5)3Th Including Formation of the Thorium Carbonyl, [(C5Me5)3Th(CO)][BPh4]

Published:2017-02-27 Issue:9 Volume:139 Page:3387-3398
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Langeslay Ryan R.¹^ORCID,Chen Guo P.¹,Windorff Cory J.¹,Chan Alan K.¹,Ziller Joseph W.¹,Furche Filipp¹^ORCID,Evans William J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States

Funder

Division of Chemistry

Basic Energy Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.6b10826

Reference96 articles.

1. Revisiting the Chemistry of the Actinocenes [(η8-C8H8)2An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η8-C8H8)2An(L)] with Thorium (L = py, 4,4′-bipy, tBuNC, R4phen)

2. Actinide-Catalyzed Intermolecular Addition of Alcohols to Carbodiimides

3. Preparation of (η5-C5Me5)2Th(bipy) and Its Reactivity toward Small Molecules

4. Thorium Triamidoamine Complexes: Synthesis of an Unusual Dinuclear Tuck-in–Tuck-over Thorium Metallacycle Featuring the Longest Known Thorium−σ-Alkyl Bond

5. Synthesis, Electrochemistry, and Reactivity of the Actinide Trisulfides [K(18-crown-6)][An(η3-S3)(NR2)3] (An = U, Th; R = SiMe3)

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