Position-Specific Secondary Deuterium Isotope Effects on Basicity of Pyridine

Author:

Perrin Charles L.1,Karri Phaneendrasai1

Affiliation:

1. Department of Chemistry & Biochemistry, University of California—San Diego, La Jolla, California 92093-0358

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference38 articles.

1. Carroll, F. A.Perspectives on Structure and Mechanism in Organic Chemistry:Brooks/Cole:Pacific Grove, CA, 1998; pp349−365.

2. Anslyn, E. V. and Dougherty, D. A.Modern Physical Organic Chemistry;University Science Books:Sausalito, CA, 2006; p421ff.

3. Intramolecular kinetic isotope effect in hydride transfer from dihydroacridine to a quinolinium ion. Rejection of a proposed two-step mechanism with a kinetically significant intermediate

4. A Mechanistic Probe for Asymmetric Reactions: Deuterium Isotope Effects at Enantiotopic Groups

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