Inter- and Intramolecular Hydrogen-Bonding Interaction of Hydroxo Groups and Steric Effect of Alkyl Substituents on Pyrazolyl Rings in TpR Ligands: Synthesis and Structural Characterization of Chloro-, Acetylacetonato-, and Hydroxo Complexes of VO2+ with TpPri2 and TpMe2 Ligands
Author:
Affiliation:
1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9806028
Reference57 articles.
1. Recent advances in poly(pyrazolyl)borate (scorpionate) chemistry
2. Alkyl, Hydride, and Hydroxide Derivatives of the s- and p-Block Elements Supported by Poly(Pyrazolyl)Borato Ligation: Models for Carbonic Anhydrase, Receptors for Anions, and the Study of Controlled Crystallographic Disorder
3. Poly (pyrazolyl)borate complexes of gallium and indium
4. Fixation of atmospheric carbon dioxide by a series of hydroxo complexes of divalent metal ions and the implication for the catalytic role of metal ion in carbonic anhydrase. Synthesis, characterization, and molecular structure of [LM(OH)]n (n = 1 or 2) and LM(.mu.-CO3)ML (M(II) = Mn, Fe, Co, Ni, Cu, Zn; L = HB(3,5-iso-Pr2pz)3)
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