Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO
Author:
Affiliation:
1. Department of Chemistry, University of Wisconsin−Madison, 1101 University Avenue, Madison, Wisconsin 53706, United States
2. Houston Technology Center, LyondellBasell, 8280 Sheldon Road, Channelview, Texas 77530, United States
Funder
National Institute of General Medical Sciences
National Science Foundation
LyondellBasell
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.4c00218
Reference48 articles.
1. Carboxylic Acids, Aliphatic
2. Transition‐Metal‐Catalyzed Carboxylation Reactions with Carbon Dioxide
3. Transition metal-catalyzed carboxylation of unsaturated substrates with CO2
4. Transition metal-mediated or catalyzed hydrocarboxylation of olefins with CO2
5. New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel
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