Chiral (SO)–N–(SO) Sulfoxide Pincer Complexes of Mg, Rh, and Ir: N–H Activation and Selective Sulfoxide Reduction upon Ligand Coordination

Author:

Locke Harald1,Herrera Alberto1,Heinemann Frank W.1,Linden Anthony1,Frieß Sibylle1,Schmid Bernhard1,Dorta Romano1

Affiliation:

1. Department Chemie und Pharmazie, Anorganische und Allgemeine Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany

Funder

Friedrich-Alexander-Universit?t Erlangen-N?rnberg

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference43 articles.

1. For a review on chiral pincer complexes, see:aRichards, C. J.; Fossey, J. S.InThe Chemistry of Pincer Compounds;Morales-Morales, D., Jensen, C. M., Eds.Elsevier:Amsterdam, 2007; p45.For structurally characterized complexes withC2-symmetricneutraltridentate ligands, see:

2. Chiral and C2-symmetrical bis(oxazolinylpyridine)rhodium(III) complexes: effective catalysts for asymmetric hydrosilylation of ketones

3. Transition-Metal Aqua Complexes of 4,6-Dibenzofurandiyl-2,2‘-bis(4-phenyloxazoline). Effective Catalysis in Diels−Alder Reactions Showing Excellent Enantioselectivity, Extreme Chiral Amplification, and High Tolerance to Water, Alcohols, Amines, and Acids

4. Chiral Sulfur Ligands for Asymmetric Catalysis

5. bFernández, I.; Khiar, N.InOrganosulfur Chemistry in Asymmetric Synthesis;Toru, T.; Bolm, C., Eds.Wiley-VCH:Weinheim, Germany, 2008; p265.

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