Chiral (SO)–N–(SO) Sulfoxide Pincer Complexes of Mg, Rh, and Ir: N–H Activation and Selective Sulfoxide Reduction upon Ligand Coordination
Author:
Affiliation:
1. Department Chemie und Pharmazie, Anorganische und Allgemeine Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany
Funder
Friedrich-Alexander-Universit?t Erlangen-N?rnberg
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.5b00178
Reference43 articles.
1. For a review on chiral pincer complexes, see:aRichards, C. J.; Fossey, J. S.InThe Chemistry of Pincer Compounds;Morales-Morales, D., Jensen, C. M., Eds.Elsevier:Amsterdam, 2007; p45.For structurally characterized complexes withC2-symmetricneutraltridentate ligands, see:
2. Chiral and C2-symmetrical bis(oxazolinylpyridine)rhodium(III) complexes: effective catalysts for asymmetric hydrosilylation of ketones
3. Transition-Metal Aqua Complexes of 4,6-Dibenzofurandiyl-2,2‘-bis(4-phenyloxazoline). Effective Catalysis in Diels−Alder Reactions Showing Excellent Enantioselectivity, Extreme Chiral Amplification, and High Tolerance to Water, Alcohols, Amines, and Acids
4. Chiral Sulfur Ligands for Asymmetric Catalysis
5. bFernández, I.; Khiar, N.InOrganosulfur Chemistry in Asymmetric Synthesis;Toru, T.; Bolm, C., Eds.Wiley-VCH:Weinheim, Germany, 2008; p265.
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