Iridium Hydride Mediated Stannane–Fluorine and −Chlorine σ-Bond Activation: Reversible Switching between X-Type Stannyl and Z-Type Stannane Ligands-Reference-Cited by-同舟云学术

Iridium Hydride Mediated Stannane–Fluorine and −Chlorine σ-Bond Activation: Reversible Switching between X-Type Stannyl and Z-Type Stannane Ligands

Published:2017-05-23 Issue:11 Volume:36 Page:2096-2106
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kameo Hajime¹^ORCID,Baba Yuki¹,Sakaki Shigeyoshi²^ORCID,Bourissou Didier³⁴^ORCID,Nakazawa Hiroshi⁵^ORCID,Matsuzaka Hiroyuki¹

Affiliation:

1. Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Gakuen-cho 1-1, Naka-ku, Sakai, Osaka 599-8531, Japan

2. Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-nishihiraki-cho 34-4, Sakyo-ku, Kyoto 606-8103, Japan

3. Université de Toulouse, UPS, Laboratoire Hétérochimie Fondamentale Appliquée, 118 route de Narbonne, F-31062 Toulouse, France

4. CNRS, LHFA UMR 5069, F-31062 Toulouse, France

5. Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto 3-3-138, Sumiyoshi-ku, Osaka 558-8585, Japan

Funder

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00137

Reference102 articles.

1. The Organometallic Chemistry of the Transition Metals

2. Bond dissociation energies:DSi–F= 540 kJ/mol,DGe–F= 485 kJ/mol,DSn–F= 467 kJ/mol,DSi–Cl= 456 kJ/mol,DGe–Cl= 432 kJ/mol,DSn–Cl= 406 kJ/mol:Lange’s Handbook of Chemistry,13th ed.Lange, N. A., Dean, J. A., Eds.McGraw-Hill:New York, 1985; pp3–131.

3. Oxidative addition reactions of saturated Si-X bonds (X = H, F, C, or Si) to Pt(PH3)2. An ab initio MO/MP4 study

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