In Situ1H NMR Studies of High-Temperature Nitroxide-Mediated Polymerization of n-Butyl Acrylate
Author:
Affiliation:
1. Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa
2. Laboratory of Polymer Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ma201216e
Reference37 articles.
1. The role of mid‐chain radicals in acrylate free radical polymerization: Branching and scission
2. Relevance of backbiting and beta-scission reactions in the free radical polymerization of Acrylonitrile
3. Structural Characterization of Nitroxide-Terminated Poly(n-butyl acrylate) Prepared in Bulk and Miniemulsion Polymerizations
4. Determination of Intramolecular Chain Transfer and Midchain Radical Propagation Rate Coefficients for Butyl Acrylate by Pulsed Laser Polymerization
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