Reactions of Perfluoroisopropyl Iodide with Cyclopentadienyl−Rhodium Complexes in Methanol. An Unexpected Route to a Rhodium−Fulvalene Complex
Author:
Affiliation:
1. Departments of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, and University of Delaware, Newark, Delaware 19716
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om010611f
Reference36 articles.
1. Ancillary Ligand-Controlled Selectivity for Metal or Cyclopentadienyl Ring Fluoroalkylation in Reactions of Fluoroalkyl Iodides with Cyclopentadienylrhodium Complexes
2. Fluoroalkylation of cobalt complexes: selective reactions at the metal or the cyclopentadienyl ring
3. Reduction pathways in lateral and diagonal (.eta.5-C5Me5)Re(CO)2Br2. Synthesis, structure, and reactivity of [(.eta.5-C5Me5)Re(CO)2Br-]
4. Bond Dissociation Energies by Kinetic Methods
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1. Nucleophilic substitution at the halogen atom (halogenophilic reactions);Russian Chemical Reviews;2012-04-30
2. Reactions of Half-Sandwich Ethene Complexes of Rhodium(I) toward Iodoperfluorocarbons: Perfluoro-alkylation or -arylation of Coordinated Ethene versus Oxidative Addition;Organometallics;2011-11-29
3. C–F Bond Activation of Highly Fluorinated Molecules at Rhodium: From Model Reactions to Catalysis;European Journal of Inorganic Chemistry;2011-01-11
4. Rhodium Organometallics;Comprehensive Organometallic Chemistry III;2007
5. Reactions of Perfluoroalkyl Iodides with M(C5H5)(CO)(PMe3) [M = Rh, Ir]; Evidence for Direct Fluoroalkylation at a CO Ligand;Organometallics;2005-11-15
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