Triniobium, Wells–Dawson-Type Polyoxoanion, [(n-C4H9)4N]9P2W15Nb3O62: Improvements in the Synthesis, Its Reliability, the Purity of the Product, and the Detailed Synthetic Procedure
Author:
Affiliation:
1. Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, United States
2. Department of Chemistry, Middle East Technical University, 06800 Ankara, Turkey
Funder
Office of Basic Energy Sciences
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic403057k
Reference28 articles.
1. Nanocluster Formation and Stabilization Fundamental Studies: Ranking Commonly Employed Anionic Stabilizers via the Development, Then Application, of Five Comparative Criteria
2. Novel Polyoxoanion- and Bu4N+-Stabilized, Isolable, and Redissolvable, 20-30-.ANG. Ir300-900 Nanoclusters: The Kinetically Controlled Synthesis, Characterization, and Mechanism of Formation of Organic Solvent-Soluble, Reproducible Size, and Reproducible Catalytic Activity Metal Nanoclusters
3. Transition Metal Nanocluster Formation Kinetic and Mechanistic Studies. A New Mechanism When Hydrogen Is the Reductant: Slow, Continuous Nucleation and Fast Autocatalytic Surface Growth
4. Nanocluster Size-Control and “Magic Number” Investigations. Experimental Tests of the “Living-Metal Polymer” Concept and of Mechanism-Based Size-Control Predictions Leading to the Syntheses of Iridium(0) Nanoclusters Centering about Four Sequential Magic Numbers
5. Additional Investigations of a New Kinetic Method To Follow Transition-Metal Nanocluster Formation, Including the Discovery of Heterolytic Hydrogen Activation in Nanocluster Nucleation Reactions
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