Anionic or Radical Polymerization Catalyzed by Metal Triflate-Based Lewis Pairs: A Comprehensive Mechanistic Study
Author:
Affiliation:
1. Department of Life Science and Applied Chemistry, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Aichi 466-8555, Japan
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.4c00830
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1. Group-transfer polymerization. 1. A new concept for addition polymerization with organosilicon initiators
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3. Steric separation of nucleophile and Lewis acid providing dramatically accelerated reaction. High-speed polymerization of methyl methacrylate with enolate-aluminum porphyrin/sterically crowded organoaluminum systems
4. Synthesis of monodispersed high molecular weight polymers and isolation of an organolanthanide(III) intermediate coordinated by a penultimate poly(MMA) unit
5. Synthesis of high molecular weight poly(methyl methacrylate) with extremely low polydispersity by the unique function of organolanthanide(III) complexes
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