Long-Chain Branched Polyethylene via Coordinative Tandem Insertion and Chain-Transfer Polymerization Using rac-{EBTHI}ZrCl2/MAO/Al–alkenyl Combinations: An Experimental and Theoretical Study

Author:

Santoro Orlando1,Piola Lorenzo1,Cabe Karl Mc2,Lhost Olivier3,Den Dauw Katty3,Vantomme Aurélien3,Welle Alexandre3,Maron Laurent2ORCID,Carpentier Jean-François1,Kirillov Evgueni1ORCID

Affiliation:

1. Univ Rennes, CNRS, Institut des Sciences Chimiques de Rennes (ISCR), UMR 6226, F-35042 Rennes, France

2. Université de Toulouse, CNRS, INSA, UPS, LPCNO, UMR 5215, 135 Avenue de Rangueil, F-31077 Toulouse Cedex 4, France

3. Total Research & Technology Feluy, Zone Industrielle Feluy C, B-7181 Seneffe, Belgium

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Reference39 articles.

1. Selectivity in Propene Polymerization with Metallocene Catalysts

2. Lai, S.Y.; Wilson, J. R.; Knight, G. W.; Stevens, J. C.; Chum, P.W. Elastic substantially linear olefin polymers. U.S. Patent 5,272,236 A, 1993 (to Dow Chemical Co.).

3. Brant, P.; Canich, J. A. M.; Dias, A. J.; Bamberger, R. L.; Licciardi, G. G.; Henrichs, P. M. Long chain branched polymers and a process to make long chain branched polymers. WO 1994007930 A1, 1994 (to ExxonMobil Chemical co.).

4. Melt rheological and thermodynamic properties of polyethylene homopolymers and poly(ethylene/?-olefin) copolymers with respect to molecular composition and structure

5. REACTION MECHANISM TO LONG-CHAIN BRANCHED PP

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