A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticles—the Case for Exploiting Pd Catalyst Speciation-Reference-Cited by-同舟云学术

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A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticles—the Case for Exploiting Pd Catalyst Speciation

Published:2021-06-21 Issue:25 Volume:143 Page:9682-9693
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Scott Neil W. J.¹,Ford Mark J.²,Jeddi Neda¹,Eyles Anthony¹,Simon Lauriane¹,Whitwood Adrian C.¹^ORCID,Tanner Theo¹,Willans Charlotte E.³^ORCID,Fairlamb Ian J. S.¹^ORCID

Affiliation:

1. Department of Chemistry, University of York, Heslington, York, North Yorkshire YO10 5DD, United Kingdom

2. Bayer AG, Alfred-Nobel-Strasse 50, 40789 Monheim, Germany

3. School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, United Kingdom

Funder

Engineering and Physical Sciences Research Council

Bayer

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.1c05294

Reference72 articles.

1. Privileged scaffolds for library design and drug discovery

2. Site-Selective Cross-Coupling of Remote Chlorides Enabled by Electrostatically Directed Palladium Catalysis

3. Regioselective (site-selective) functionalisation of unsaturated halogenated nitrogen, oxygen and sulfur heterocycles by Pd-catalysed cross-couplings and direct arylation processes

4. Site-selective Suzuki–Miyaura coupling of heteroaryl halides – understanding the trends for pharmaceutically important classes

5. Origin of Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions of Polyhalogenated Heterocycles

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1. Synthesis, structure determination of Schiff bases and their PdII complexes and investigation of palladium catalyzed cross-coupling reactions;Journal of Molecular Structure;2025-01

2. Revealing the Hidden Complexity and Reactivity of Palladacyclic Precatalysts: The P(o-tolyl)₃ Ligand Enables a Cocktail of Active Species Utilizing the Pd(II)/Pd(IV) and Pd(0)/Pd(II) Pathways for Efficient Catalysis;ACS Catalysis;2024-08-09

3. Oxidative Addition of (Hetero)aryl (Pseudo)halides at Palladium(0): Origin and Significance of Divergent Mechanisms;Journal of the American Chemical Society;2024-07-03

4. Synergistic effects of oxygen vacancies and Pd single atoms on Pd@TiO2− for efficient HER catalysis;Chinese Chemical Letters;2024-07

5. Deciphering complexity in Pd–catalyzed cross-couplings;Nature Communications;2024-05-10

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