Ir-Catalyzed Substitution of Propargylic-type Esters with Enoxysilanes

Author:

Matsuda Isamu1,Komori Ken-ichi1,Itoh Kenji1

Affiliation:

1. Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference17 articles.

1. (a) Hudrlik, P. F.; Hudrlik, A. M. InThe Chemistry of the Carbon−Carbon TripleBond; Patai, S., Ed.; John Wiley & Sons:  Chester, 1978; Chapter 7, p 199.

2. Review articles:  (a) Nicholas, K. M.Acc. Chem. Res.1987,20, 27. (b) Caffyn, A. J. M.; Nicholas, K. M. InComprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, J., Eds.; Pergamon Press:  Oxford, 1995; Vol. 12, Chapter 7.1, p 685. (c) Green, J. R.Curr. Org. Chem.2001,5, 809. Original papers:  (d) Nicholas, K. M.; Mulvaney, M.; Bayer, M.J.Am. Chem. Soc.1980,102, 2508. (e) Kuhn, O.; Rau, D.; Mayr, H.J. Am.Chem. Soc.1998,120, 900.

3. A general strategy using η2co2(co)6 acetylene complexes for the synthesis of the enediyne antitumor agents esperamicin, calicheamicin, dy

4. Highly stereocontrolled total synthesis of (+)-bengamide E

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