Unusually Large Primary 2H/H Kinetic Isotope Effects Accompanying a syn-β-H Elimination Reaction in a σ-Alkyl−Palladium Complex
Author:
Affiliation:
1. The Bristol Centre for Organometallic Catalysis, The School of Chemistry, Bristol, BS8 1TS, UK
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja039349n
Reference14 articles.
1. Carbonhydrogen-transition metal bonds
2. Beller, M.; Riermeir, T. H.; Stark, G.Transition Metals for OrganicSynthesis; Beller, M., Bolm, C., Eds.; Wiley-VCH: Weinheim, 1998; Vol. 1, pp 209−240.
3. Mechanism of the Palladium-Catalyzed Elimination of Acetic Acid from Allylic Acetates
4. On the Nature of the Catalytic Palladium-Mediated Elimination of Allylic Carbonates and Acetates To Form 1,3-Dienes
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