Use of Kinetic Isotope Effects in Mechanism Studies. 5.1 Isotope Effects and Element Effects Associated with Hydron-Transfer Steps during Alkoxide-Promoted Dehydrohalogenations-Reference-Cited by-同舟云学术

Use of Kinetic Isotope Effects in Mechanism Studies. 5.1 Isotope Effects and Element Effects Associated with Hydron-Transfer Steps during Alkoxide-Promoted Dehydrohalogenations

Published:1997-10-01 Issue:42 Volume:119 Page:9965-9974
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Koch Heinz F.¹,Lodder Gerrit¹,Koch Judith G.¹,Bogdan David J.¹,Brown Geoffrey H.¹,Carlson Carrie A.¹,Dean Amy B.¹,Hage Ronald¹,Han Patrick¹,Hopman Johan C. P.¹,James Lisa A.¹,Knape Petra M.¹,Roos Eric C.¹,Sardina Melissa L.¹,Sawyer Rachael A.¹,Scott Barbara O.¹,Testa Charles A.¹,Wickham Steven D.¹

Affiliation:

1. Contribution from the Department of Chemistry, Ithaca College, Ithaca, New York 14850, and the Leiden Institute of Chemistry, Gorlaeus Laboratories, University of Leiden, Leiden 2300RA, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja970189n

Reference42 articles.

1. Use of kinetic isotope effects in mechanism studies. 4. Chlorine isotope effects associated with alkoxide-promoted dehydrochlorination reactions

2. Kinetic arguments for the existence of hydrogen bonded carbanion intermediates during dehydrohalogenation reactions of C6H5CHClCF2Y

3. Use of kinetic isotope effects in mechanism studies. Anomalous Arrhenius parameters in the study of elimination reactions

4. Proton-transfer reactions between carbon and oxygen

5. Proton-transfer reactions. I. Partitioning of carbanion intermediates generated by reactions of alkenes with alkoxide ions in alcohol

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