Preference for Eclipsed Conformations in Acyclic Neopentyldialkylamines and the Stereodynamical Consequences: An NMR and Molecular Mechanics Investigation1
Author:
Affiliation:
1. Contribution from the Chemistry Department, University College, Gower Street, London WC1 E6BT, U.K., and Department of Organic Chemistry “A. Mangini”, University of Bologna, Viale Risorgimento 4, Bologna 40136, Italy
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9710363
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3. (b) Dhar, R. K.; Sygula, A.; Fronczek, F. R.; Rabideau, P. W.Tetrahedron1992,48, 9417.
4. Conformational analysis of 1,3-dioxanes with sulfide, sulfoxide and sulfone substitution at C(5). Finding an eclipsed conformation in cis-2-tert-butyl-5-(tert-butylsulfonyl)-1,3-dioxane
5. Conformational analysis of 5-substituted 1,3-dioxanes. 5. Bond eclipsing in tert-butylsulfonyl substituted 1,3-dioxanes and cyclohexanes. X-ray diffraction studies, MMP2 calculations, and interpretation
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