Preparation, Structure, Bonding, and Preliminary Reactivity of a Six-Coordinate d4 Osmium

Preparation, Structure, Bonding, and Preliminary Reactivity of a Six-Coordinate d4 Osmium–Boryl Complex

Published:2012-06-18 Issue:13 Volume:31 Page:4646-4649
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Esteruelas Miguel A.¹,Fernández Israel²,López Ana M.¹,Mora Malka¹,Oñate Enrique¹

Affiliation:

1. Departamento de Quı́mica Inorgánica-Instituto de Sı́ntesis Quı́mica y Catálisis Homogénea (ISQCH), Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain

2. Departamento de Quı́mica Orgánica I, Facultad de Ciencias Quı́micas, Universidad Complutense de Madrid, 28040 Madrid, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om300407d

Reference51 articles.

1. Molecular structure of Mo(CO)2[S2CN-i-Pr2]2. A trigonal-prismatic electron-deficient molybdenum(II) carbonyl derivative

2. Deformations from octahedral geometry in d4 transition-metal complexes

3. Analysis of the Aromaticity of Osmabicycles Analogous to the Benzimidazolium Cation

4. Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(PR3)2 (PR3 = P-i-Pr3, PMe-t-Bu2)

5. Synthesis and X-ray Structure of the Unusual Cysteine-Complex OsH2{OC(=O)CH[NHC(=O)CH3]CH2S}(PiPr3)2

Cited by 22 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Quantifying variation in cooperative B–H bond activations using Os(ii) and Os(iii) κ²-N,S-chelated complexes: same, but different;Chemical Science;2024

2. From trihydroborates to bisborylenes: a route to dinuclear bisborylene complexes;Chemical Communications;2022

3. Contemporary developments in transition metal boryl complexes: An overview;Coordination Chemistry Reviews;2021-11

4. Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism;Organometallics;2020-05-21

5. Sigma-bond activation reactions induced by unsaturated Os(IV)-hydride complexes;Advances in Organometallic Chemistry;2020