Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand-Reference-Cited by-同舟云学术

Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand

Published:2014-07-31 Issue:32 Volume:136 Page:11300-11303
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Xiong Yun¹,Szilvási Tibor²,Yao Shenglai¹,Tan Gengwen¹,Driess Matthias¹

Affiliation:

1. Institute of Chemistry: Metalorganics and Inorganic Materials, Technische Universität Berlin, Strasse des 17. Juni 135, Sekr. C2, D-10623 Berlin, Germany

2. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Szent Gellért tér 4, 1111 Budapest, Hungary

Funder

Deutsche Forschungsgemeinschaft

Hungary National Development Agency

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja506824s

Reference31 articles.

1. Homogeneous syngas conversion

2. Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex

3. Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand

4. Donor/acceptor stabilization of Ge(ii) dihydride

5. Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal

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