Parabolic Relationship between the Basicity of the Nucleophile and π-Face Selection in Addition of the Substituted Acetylide Ions to Cyclohexanone and Cyclohexanethione-Reference-Cited by-同舟云学术

Parabolic Relationship between the Basicity of the Nucleophile and π-Face Selection in Addition of the Substituted Acetylide Ions to Cyclohexanone and Cyclohexanethione

Published:1998-01-22 Issue:3 Volume:63 Page:521-530
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Cieplak Andrzej Stanislaw¹

Affiliation:

1. Department of Chemistry, Yale University, New Haven, Connecticut 06520, and Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo9713722

Reference58 articles.

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4. Stereochemistry of nucleophilic addition to cyclohexanone. The importance of two-electron stabilizing interactions

5. Reversal of .pi.-facial diastereoselection upon electronegative substitution of the substrate and the reagent

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