Comparison of the Catalytic Activity of [(η5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(η5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions
Author:
Affiliation:
1. The Guelph-Waterloo Centre for Graduate Work in Chemistry, (GWC)2, Department of Chemistry, University of Guelph, Guelph, Ontario, Canada N1G 2W1
2. Department of Chemistry McMaster University, Hamilton, Ontario, Canada L8S 4M1
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400871v
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1. Asymmetric Transfer Hydrogenation Catalyzed by Chiral Ruthenium Complexes
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3. Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes
4. Catalytic hydrogenation of polar organic functionalities based on Ru-mediated heterolytic dihydrogen cleavage
5. Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes
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