Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry

Author:

Paradas Miguel1,Campaña Araceli G.1,Jiménez Tania1,Robles Rafael1,Oltra J. Enrique1,Buñuel Elena1,Justicia José1,Cárdenas Diego J.1,Cuerva Juan M.1

Affiliation:

1. Department of Organic Chemistry, Faculty of Sciences, University of Granada, Campus Fuentenueva s/n, E-18071 Granada, Spain, and Department of Organic Chemistry, Faculty of Sciences, Universidad Autónoma de Madrid, Cantoblanco E-28049, Madrid, Spain

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference63 articles.

1. aCurran, D. P., Porter, N. A., and Giese, B.Stereochemistry of Radical Reactions;VCH:Weinheim, Germany, 1996; p4.

2. bCurran, D. P.In Comprehensive Organic Synthesis;Trost, B. M., Fleming, I., and Semmelhack, M. E., Eds.Pergamon:Oxford, 1991; Vol. 4, pp715−777

3. HAT mechanism is a subfamily of the more general proton-coupled electron transfer (PCET) mechanism:

4. PROTON-COUPLED ELECTRON TRANSFER: A Reaction Chemist's View

5. Proton-Coupled Electron Transfer

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